Iron production was a particularly important precolonial African technology, with iron becoming a central component of socioeconomic life in many societies across the continent. Iron-bearing ores are much more abundant in the earth’s crust than those of copper, and in Africa, iron was recovered from these ores using the bloomery process, until the importation of European iron in the later second millennium eventually undermined local production. Although smelting was most intensively focused in regions where all the necessary components of a smelt were plentiful—iron ore, ceramic, fuel, and water—frequent occurrences of small-scale, local iron production mean that iron slag and associated remains are common finds on archaeological sites across Africa. The archaeological remains found on iron production and iron-working sites can provide detailed information about the past processes that were undertaken at these sites, as well as the people involved with the technologies both as practitioners and consumers. A variety of analytical approaches are commonly used by archaeometallurgists to learn more about past iron technologies, particularly those methods that explore the chemistry and mineralogy of archaeological samples. By interpreting the results of these analyses in conjunction with ethnographic, historical, and experimental data, it is possible to reconstruct the techniques and ingredients that past smelters and smiths employed in their crafts, and address important questions concerning the organization of production, the acquisition of raw materials, innovations and changes in technological approach, and the environmental and social changes that accompanied these technologies.