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Condensation Calculations in Planetary Science and Cosmochemistry  

Denton S. Ebel

The Sun’s chemical and isotopic composition records the composition of the solar nebula from which the planets formed. If a piece of the Sun is cooled to 1,000 K at 1 mbar total pressure, a mineral assemblage is produced that is consistent with the minerals found in the least equilibrated (most chemically heterogeneous), oldest, and compositionally Sunlike (chondritic), hence most “primitive,” meteorites. This is an equilibrium or fractional condensation experiment. The result can be simulated by calculations using equations of state for hundreds of gaseous molecules, condensed mineral solids, and silicate liquids, the products of a century of experimental measurements and recent theoretical studies. Such calculations have revolutionized our understanding of the chemistry of the cosmos. The mid-20th century realization that meteorites are fossil records of the early solar system made chemistry central to understanding the origin of the Earth, Moon, and other bodies. Thus “condensation,” more generally the distribution of elements and isotopes between vapor and condensed solids and/or liquids at or approaching chemical equilibrium, came to deeply inform discussion of how meteoritic and cometary compositions bear on the origins of atmospheres and oceans and the differences in composition among the planets. This expansion of thinking has had profound effects upon our thinking about the origin and evolution of Earth and the other worlds of our solar system. Condensation calculations have also been more broadly applied to protoplanetary disks around young stars, to the mineral “rain” of mineral grains expected to form in cool dwarf star atmospheres, to the expanding circumstellar envelopes of giant stars, to the vapor plumes expected to form in giant planetary impacts, and to the chemically and isotopically distinct “shells” computed and observed to exist in supernovae. The beauty of equilibrium condensation calculations is that the distribution of elements between gaseous molecules, solids, and liquids is fixed by temperature, total pressure, and the overall elemental composition of the system. As with all sophisticated calculations, there are inherent caveats, subtleties, and computational difficulties. In particular, local equilibrium chemistry has yet to be consistently integrated into gridded, dynamical astrophysical simulations so that effects like the blocking of light and heat by grains (opacity), absorption and re-emission of light by grains (radiative transfer), and buffering of heat by grain evaporation/condensation are fed back into the physics at each node or instance of a gridded calculation over time. A deeper integration of thermochemical computations of chemistry with physical models makes the prospect of a general protoplanetary disk model as hopeful in the 2020s as a general circulation model for global climate may have been in the early 1970s.


Solar Elemental Abundances  

Katharina Lodders

Solar elemental abundances, or solar system elemental abundances, refer to the complement of chemical elements in the entire Solar System. The Sun contains more than 99% of the mass in the solar system and therefore the composition of the Sun is a good proxy for the composition of the overall solar system. The solar system composition can be taken as the overall composition of the molecular cloud within the interstellar medium from which the solar system formed 4.567 billion years ago. Active research areas in astronomy and cosmochemistry model collapse of a molecular cloud of solar composition into a star with a planetary system and the physical and chemical fractionation of the elements during planetary formation and differentiation. The solar system composition is the initial composition from which all solar system objects (the Sun, terrestrial planets, gas giant planets, planetary satellites and moons, asteroids, Kuiper-belt objects, and comets) were derived. Other dwarf stars (with hydrostatic hydrogen-burning in their cores) like the Sun (type G2V dwarf star) within the solar neighborhood have compositions similar to the Sun and the solar system composition. In general, differential comparisons of stellar compositions provide insights about stellar evolution as functions of stellar mass and age and ongoing nucleosynthesis but also about galactic chemical evolution when elemental compositions of stellar populations across the Milky Way Galaxy is considered. Comparisons to solar composition can reveal element destruction (e.g., Li) in the Sun and in other dwarf stars. The comparisons also show element production of, for example, C, N, O, and the heavy elements made by the s-process in low to intermediate mass stars (3–7 solar masses) after these evolved from their dwarf-star stage into red giant stars (where hydrogen and helium burning can occur in shells around their cores). The solar system abundances are and have been a critical test composition for nucleosynthesis models and models of galactic chemical evolution, which aim ultimately to track the production of the elements heavier than hydrogen and helium in the generation of stars that came forth after the Big Bang 13.4 billion years ago.


Steam Atmospheres and Magma Oceans on Planets  

Keiko Hamano

A magma ocean is a global layer of partially or fully molten rocks. Significant melting of terrestrial planets likely occurs due to heat release during planetary accretion, such as decay heat of short-lived radionuclides, impact energy released by continuous planetesimal accretion, and energetic impacts among planetary-sized bodies (giant impacts). Over a magma ocean, all water, which is released upon impact or degassed from the interior, exists as superheated vapor, forming a water-dominated, steam atmosphere. A magma ocean extending to the surface is expected to interact with the overlying steam atmosphere through material and heat exchange. Impact degassing of water starts when the size of a planetary body becomes larger than Earth’s moon or Mars. The degassed water could build up and form a steam atmosphere on protoplanets growing by planetesimal accretion. The atmosphere has a role in preventing accretion energy supplied by planetesimals from escaping, leading to the formation of a magma ocean. Once a magma ocean forms, part of the steam atmosphere would start to dissolve into the surface magma due to the high solubility of water into silicate melt. Theoretical studies indicated that as long as the magma ocean is present, a negative feedback loop can operate to regulate the amount of the steam atmosphere and to stabilize the surface temperature so that a radiative energy balance is achieved. Protoplanets can also accrete the surrounding H 2 -rich disk gas. Water could be produced by oxidation of H 2 by ferrous iron in the magma. The atmosphere and water on protoplanets could be a mixture of outgassed and disk-gas components. Planets formed by giant impact would experience a global melting on a short timescale. A steam atmosphere could grow by later outgassing from the interior. Its thermal blanketing and greenhouse effects are of great importance in controlling the cooling rate of the magma ocean. Due to the presence of a runaway greenhouse threshold, the crystallization timescale and water budget of terrestrial planets can depend on the orbital distance from the host star. The terrestrial planets in our solar system essentially have no direct record of their earliest history, whereas observations of young terrestrial exoplanets may provide us some insight into what early terrestrial planets and their atmosphere are like. Evolution of protoplanets in the framework of pebble accretion remains unexplored.


The Formation and Evolution of the Solar System  

Mikhail Marov

The formation and evolution of our solar system (and planetary systems around other stars) are among the most challenging and intriguing fields of modern science. As the product of a long history of cosmic matter evolution, this important branch of astrophysics is referred to as stellar-planetary cosmogony. Interdisciplinary by way of its content, it is based on fundamental theoretical concepts and available observational data on the processes of star formation. Modern observational data on stellar evolution, disc formation, and the discovery of extrasolar planets, as well as mechanical and cosmochemical properties of the solar system, place important constraints on the different scenarios developed, each supporting the basic cosmogony concept (as rooted in the Kant-Laplace hypothesis). Basically, the sequence of events includes fragmentation of an original interstellar molecular cloud, emergence of a primordial nebula, and accretion of a protoplanetary gas-dust disk around a parent star, followed by disk instability and break-up into primary solid bodies (planetesimals) and their collisional interactions, eventually forming a planet. Recent decades have seen major advances in the field, due to in-depth theoretical and experimental studies. Such advances have clarified a new scenario, which largely supports simultaneous stellar-planetary formation. Here, the collapse of a protosolar nebula’s inner core gives rise to fusion ignition and star birth with an accretion disc left behind: its continuing evolution resulting ultimately in protoplanets and planetary formation. Astronomical observations have allowed us to resolve in great detail the turbulent structure of gas-dust disks and their dynamics in regard to solar system origin. Indeed radio isotope dating of chondrite meteorite samples has charted the age and the chronology of key processes in the formation of the solar system. Significant progress also has been made in the theoretical study and computer modeling of protoplanetary accretion disk thermal regimes; evaporation/condensation of primordial particles depending on their radial distance, mechanisms of clustering, collisions, and dynamics. However, these breakthroughs are yet insufficient to resolve many problems intrinsically related to planetary cosmogony. Significant new questions also have been posed, which require answers. Of great importance are questions on how contemporary natural conditions appeared on solar system planets: specifically, why the three neighbor inner planets—Earth, Venus, and Mars—reveal different evolutionary paths.