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Condensation Calculations in Planetary Science and Cosmochemistry  

Denton S. Ebel

The Sun’s chemical and isotopic composition records the composition of the solar nebula from which the planets formed. If a piece of the Sun is cooled to 1,000 K at 1 mbar total pressure, a mineral assemblage is produced that is consistent with the minerals found in the least equilibrated (most chemically heterogeneous), oldest, and compositionally Sunlike (chondritic), hence most “primitive,” meteorites. This is an equilibrium or fractional condensation experiment. The result can be simulated by calculations using equations of state for hundreds of gaseous molecules, condensed mineral solids, and silicate liquids, the products of a century of experimental measurements and recent theoretical studies. Such calculations have revolutionized our understanding of the chemistry of the cosmos. The mid-20th century realization that meteorites are fossil records of the early solar system made chemistry central to understanding the origin of the Earth, Moon, and other bodies. Thus “condensation,” more generally the distribution of elements and isotopes between vapor and condensed solids and/or liquids at or approaching chemical equilibrium, came to deeply inform discussion of how meteoritic and cometary compositions bear on the origins of atmospheres and oceans and the differences in composition among the planets. This expansion of thinking has had profound effects upon our thinking about the origin and evolution of Earth and the other worlds of our solar system. Condensation calculations have also been more broadly applied to protoplanetary disks around young stars, to the mineral “rain” of mineral grains expected to form in cool dwarf star atmospheres, to the expanding circumstellar envelopes of giant stars, to the vapor plumes expected to form in giant planetary impacts, and to the chemically and isotopically distinct “shells” computed and observed to exist in supernovae. The beauty of equilibrium condensation calculations is that the distribution of elements between gaseous molecules, solids, and liquids is fixed by temperature, total pressure, and the overall elemental composition of the system. As with all sophisticated calculations, there are inherent caveats, subtleties, and computational difficulties. In particular, local equilibrium chemistry has yet to be consistently integrated into gridded, dynamical astrophysical simulations so that effects like the blocking of light and heat by grains (opacity), absorption and re-emission of light by grains (radiative transfer), and buffering of heat by grain evaporation/condensation are fed back into the physics at each node or instance of a gridded calculation over time. A deeper integration of thermochemical computations of chemistry with physical models makes the prospect of a general protoplanetary disk model as hopeful in the 2020s as a general circulation model for global climate may have been in the early 1970s.

Article

The Formation of the Martian Moons  

Pascal Rosenblatt, Ryuki Hyodo, Francesco Pignatale, Antony Trinh, Sebastien Charnoz, Kevin Dunseath, Mariko Dunseath-Terao, and Hidenori Genda

The origin of the natural satellites or moons of the solar system is as challenging to unravel as the formation of the planets. Before the start of the space probe exploration era, this topic of planetary science was restricted to telescopic observations, which limited the possibility of testing different formation scenarios. This era has considerably boosted this topic of research, particularly after the Apollo missions returned samples from the Moon’s surface to Earth. Observations from subsequent deep space missions such as Viking 1 and 2 Orbiters, Voyager 1 and 2, Phobos-2, Galileo, Cassini-Huygens, and the most recent Mars orbiters such as Mars Express, as well as from the Hubble space telescope, have served to intensify research in this area. Each moon system has its own specificities, with different origins and histories. It is widely accepted that the Earth’s Moon formed after a giant collision between the proto-Earth and a body similar in size to Mars. The Galilean moons of Jupiter, on the other hand, appear to have formed by accretion in a circum-Jovian disk, while smaller, irregularly shaped satellites were probably captured by the giant planet. The small and medium-sized Saturnian moons may have formed from the rings encircling the planet. Among the terrestrial planets, Mercury and Venus have no moons, the Earth has a single large moon, and Mars has two very small satellites. This raises some challenging questions: What processes can lead to moon formation around terrestrial planets and what parameters determine the possible outcomes, such as the number and size of moons? The answer to such fundamental questions necessarily entails a thorough understanding of the formation of the Martian system and may have relevance to the possible existence of (exo)moons orbiting exoplanets. The formation of such exomoons is of great importance as they could influence conditions for habitability or for maintaining life over long periods of time on the surface of Earth-like exoplanets, for example by limiting the variations of the orientation of the planet’s rotation axis and thus preventing frequent changes of its climate. Our current knowledge concerning the origin of Phobos and Deimos has been acquired from observational data as well as theoretical work. Early observations led to the idea that the two satellites were captured asteroids but this created difficulties in reconciling the current orbits of Phobos and Deimos with those of captured bodies, hence suggesting the need for an alternative theory. A giant-impact scenario provides a description of how moons similar to Phobos and Deimos can be formed in orbits similar to those observed today. This scenario also restricts the range of possible composition of the two moons, providing a motivation for future missions that aim for the first time to bring material from the Martian system back to Earth.