Planetary Atmospheres and Oceans

The atmosphere of Mars, like most planetary atmospheres, consists of molecules absorbing and emitting in the infrared (IR) and of particles (dust or clouds) that also interact with the IR radiation. This makes the IR spectral range highly effective for the study of the atmospheric composition and thermal structure. Since the first missions to Mars, infrared spectrometers have been used to study the atmosphere. Thermal IR instruments, which sense the emission from the surface and the atmosphere of Mars, as well as near-IR spectrometers, sensitive to the reflected solar radiation, deliver the three-dimensional structure of the atmosphere and permit monitoring of the CO2, H2O, CO, and aerosol cycles over Mars’s seasons. IR spectroscopy at high spectral resolution from the ground or from orbit is the most commonly used method to search for unknown species and to monitor the known minor components of the Martian atmosphere. It is also used to study isotopic ratios essential for understanding the volatile evolution on the planet.

The Martian ionosphere is a plasma embedded within the neutral upper atmosphere of the planet. Its main source is the ionization of the CO2-dominated Martian mesosphere and thermosphere by energetic EUV solar radiation. The ionosphere of Mars is subject to an important variability induced by changes in its forcing mechanisms (e.g., the UV solar flux) and by variations in the neutral atmosphere (e.g., the presence of global dust storms, atmospheric waves and tides, changes in atmospheric composition, etc.). Its vertical structure is dominated by a maximum in electron concentration at altitude about 120–140 km, coincident with the peak of the ionization rate. Below, there is a secondary peak produced by solar X-rays and photoelectron-impact ionization. A sporadic third layer, possibly of meteoric origin, has been also detected below. The most abundant ion in the Martian ionosphere is O2 +, although O+ can become more abundant in the upper ionospheric layers. While below about 180–200 km the Martian ionosphere is dominated by photochemical processes, above those altitudes the dynamics of the plasma becomes more important. The ionosphere is also an important source of escaping particles via processes such as dissociative recombination of ions or ion pickup. So, characterization of the ionosphere provides or can provide information about such disparate systems and processes as solar radiation reaching the planet, the neutral atmosphere, meteoric influx, atmospheric escape to space, or the interaction of the planet with the solar wind. It is thus not surprising that the interest about this region dates from the beginning of the space era. From the first measurements provided by the Mariner 4 mission in the 1960s to observations by the Mars Express and MAVEN orbiters in the 2010s, our knowledge of this atmospheric region is the consequence of the accumulation of more than 50 years of discontinuous measurements by different space missions. Numerical simulations by computational models able to simulate the processes that shape the ionosphere have also been commonly employed to obtain information about this region, to provide an interpretation of the observations and to fill their gaps. As a result, at the end of the 2010s the Martian ionosphere was the best known one after that of the Earth. However, there are still areas for which our knowledge is far from being complete. Examples are the details and balance of the mechanisms populating the nightside ionosphere, the origin and variability of the lower ionospheric peak, and the precise mechanisms shaping the topside ionosphere.

Planetary spectroscopy uses physical methods to study the chemical properties of the geological materials on the planetary bodies in our solar system. This article will present twelve types of spectroscopy frequently used in planetary explorations. Their energy (or wavelength) varies from γ-ray (keV) to far-infrared (μm), which involves the transitions of nuclei, atoms, ions, and molecules in planetary materials. The article will cover the basic concept of the transition for each of the twelve types of spectroscopy, along with their legendary science discoveries made during the past planetary exploration missions by the international planetary science and engineering community. The broad application of spectroscopy in planetary exploration is built upon the fact that only limited extraterrestrial materials were collected (meteorites, cosmic dust, and the returned samples by missions) that enabled the detailed investigations of their properties in laboratories, while spectroscopic measurements can be made on the objects of our solar system remotely and robotically, such as during the flyby, orbiting, lander, and rover missions. In this sense, the knowledge obtained by planetary spectroscopy has contributed to a major portion of planetary sciences. In the coming era of space explorations, more powerful spacecraft will be sent out by mankind, go to deep space, and explore exotic places. Generations of new planetary science payloads, including planetary spectrometers, will be created and will fly. New sciences will be revealed.

Uranus provides a unique laboratory to test current understanding of planetary atmospheres under extreme conditions. Multi-spectral observations from Voyager, ground-based observatories, and space telescopes have revealed a delicately banded atmosphere punctuated by storms, waves, and dark vortices, evolving slowly under the seasonal influence of Uranus’s extreme axial tilt. Condensables like methane and hydrogen sulphide play a crucial role in shaping circulation, clouds, and storm phenomena via latent heat release through condensation, strong equator-to-pole gradients suggestive of equatorial upwelling and polar subsidence, and the formation of stabilizing layers that may decouple different circulation and convective regimes as a function of depth. Phase transitions in the watery depths may also decouple Uranus’s atmosphere from motions within the interior. Weak vertical mixing and low atmospheric temperatures associated with Uranus’s negligible internal heat means that stratospheric methane photochemistry occurs in a unique high-pressure regime, decoupled from the influx of external oxygen. The low homopause also allows for the formation of an extensive ionosphere. Finally, the atmosphere provides a window on the bulk composition of Uranus—the ice-to-rock ratio, supersolar elemental and isotopic enrichments inferred from remote sensing, and future in situ measurements—providing key insights into its formation and subsequent migration. As a cold, hydrogen-dominated, intermediate-sized, slowly rotating, and chemically enriched world, Uranus could be the closest and best example of atmospheric processes on a class of worlds that may dominate the census of planets beyond our own solar system. Future missions to the Uranian system must carry a suite of instrumentation capable of advancing knowledge of the time-variable circulation, composition, meteorology, chemistry, and clouds on this enigmatic “ice giant.”