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Article

A. Määttänen and F. Montmessin

Although resembling an extremely dry desert, planet Mars hosts clouds in its atmosphere. Every day somewhere on the planet a part of the tiny amount of water vapor held by the atmosphere can condense as ice crystals to form mainly cirrus-type clouds. The existence of water ice clouds has been known for a long time and they have been studied for decades, leading to the establishment of a well-known climatology and understanding on their formation and properties. Despite their thinness, they have a clear impact on the atmospheric temperatures, thus affecting the Martian climate. Another, more exotic type of clouds forms as well on Mars. The atmospheric temperatures can plunge to such frigid values that the major gaseous component of the atmosphere, CO2, condenses as ice crystals. These clouds form in the cold polar night where they also contribute to the formation of the CO2 ice polar cap, and also in the mesosphere at very high altitudes, near the edge of space, analogously to the noctilucent clouds on Earth. The mesospheric clouds, discovered in the early 2000s, have put our understanding of the Martian atmosphere to a test. On Mars, cloud crystals form on ice nuclei, mostly provided by the omnipresent mineral dust. Thus, the clouds link the three major climatic cycles: those of the two major volatiles, H2O and CO2, and that of dust, which is a major climatic agent itself.

Article

Nuno C. Santos, Susana C.C. Barros, Olivier D.S. Demangeon, and João P. Faria

Is the Solar System unique, or are planets ubiquitous in the universe? The answer to this long-standing question implies the understanding of planet formation, but perhaps more relevant, the observational assessment of the existence of other worlds and their frequency in the galaxy. The detection of planets orbiting other suns has always been a challenging task. Fortunately, technological progress together with significant development in data reduction and analysis processes allowed astronomers to finally succeed. The methods used so far are mostly based on indirect approaches, able to detect the influence of the planets on the stellar motion (dynamical methods) or the planet’s shadow as it crosses the stellar disk (transit method). For a growing number of favorable cases, direct imaging has also been successful. The combination of different methods also allowed probing planet interiors, composition, temperature, atmospheres, and orbital architecture. Overall, one can confidently state that planets are common around solar-type stars, low mass planets being the most frequent among them. Despite all the progress, the discovery and characterization of temperate Earth-like worlds, similar to the Earth in both mass and composition and thus potential islands of life in the universe, is still a challenging task. Their low amplitude signals are difficult to detect and are often submerged by the noise produced by different instrumentation sources and astrophysical processes. However, the dawn of a new generation of ground and space-based instruments and missions is promising a new era in this domain.

Article

Leigh N. Fletcher

Uranus provides a unique laboratory to test current understanding of planetary atmospheres under extreme conditions. Multi-spectral observations from Voyager, ground-based observatories, and space telescopes have revealed a delicately banded atmosphere punctuated by storms, waves, and dark vortices, evolving slowly under the seasonal influence of Uranus’s extreme axial tilt. Condensables like methane and hydrogen sulphide play a crucial role in shaping circulation, clouds, and storm phenomena via latent heat release through condensation, strong equator-to-pole gradients suggestive of equatorial upwelling and polar subsidence, and the formation of stabilizing layers that may decouple different circulation and convective regimes as a function of depth. Phase transitions in the watery depths may also decouple Uranus’s atmosphere from motions within the interior. Weak vertical mixing and low atmospheric temperatures associated with Uranus’s negligible internal heat means that stratospheric methane photochemistry occurs in a unique high-pressure regime, decoupled from the influx of external oxygen. The low homopause also allows for the formation of an extensive ionosphere. Finally, the atmosphere provides a window on the bulk composition of Uranus—the ice-to-rock ratio, supersolar elemental and isotopic enrichments inferred from remote sensing, and future in situ measurements—providing key insights into its formation and subsequent migration. As a cold, hydrogen-dominated, intermediate-sized, slowly rotating, and chemically enriched world, Uranus could be the closest and best example of atmospheric processes on a class of worlds that may dominate the census of planets beyond our own solar system. Future missions to the Uranian system must carry a suite of instrumentation capable of advancing knowledge of the time-variable circulation, composition, meteorology, chemistry, and clouds on this enigmatic “ice giant.”

Article

Athena Coustenis

Titan, Saturn’s largest satellite, is one of the most intriguing moons in our Solar System, in particular because of its dense and extended nitrogen-based and organic-laden atmosphere. Other unique features include a methanological cycle similar to the Earth’s hydrological one, surface features similar to terrestrial ones, and a probable under-surface liquid water ocean. Besides the dinitrogen main component, the gaseous content includes methane and hydrogen, which, through photochemistry and photolysis, produce a host of trace gases such as hydrocarbons and nitriles. This very advanced organic chemistry creates layers of orange-brown haze surrounding the satellite. The chemical compounds diffuse downward in the form of aerosols and condensates and are finally deposited on the surface. There is very little oxygen in the atmosphere, mainly in the form of H2O, CO, and CO2. The atmospheric chemical and thermal structure varies significantly with seasons, much like on Earth, albeit on much longer time scales. Extensive analysis of Titan data from ground, Earth-orbiting observatories, and space missions, like those returned by the 13-year operating Cassini-Huygens spacecraft, reveals a complex system with strong interactions among the atmosphere, the surface, and the interior. The processes operating in the atmosphere are informative of what occurs on Earth and give hints as to the origin and evolution of our outer Solar System.

Article

Dmitry V. Bisikalo, Pavel V. Kaygorodov, and Valery I. Shematovich

The history of exoplanetary atmospheres studies is strongly based on the observations and investigations of the gaseous envelopes of hot Jupiters—exoplanet gas giants that have masses comparable to the mass of Jupiter and orbital semi-major axes shorter than 0.1 AU. The first exoplanet around a solar-type star was a hot Jupiter discovered in 1995. Researchers found an object that had completely atypical parameters compared to planets known in the solar system. According to their estimates, the object might have a mass about a half of the Jovian mass and a very short orbital period (four days), which means that it has an orbit roughly corresponding to the orbit of Mercury. Later, many similar objects were discovered near different stars, and they acquired a common name—hot Jupiters. It is still unclear what the mechanism is for their origin, because generally accepted theories of planetary evolution predict the formation of giant planets only at large orbital distances, where they can accrete enough matter before the protoplanetary disc disappears. If this is true, before arriving at such low orbits, hot Jupiters might have a long migration path, caused by interactions with other massive planets and/or with the gaseous disc. In favor of this model is the discovery of many hot Jupiters in elliptical and highly inclined orbits, but on the other hand several observed hot Jupiters have circular orbits with low inclination. An alternative hypothesis is that the cores of future hot Jupiters are super-Earths that may later intercept matter from the protoplanetary disk falling on the star. The scientific interest in hot Jupiters has two aspects. The first is the peculiarity of these objects: they have no analogues in the solar system. The second is that, until recently, only for hot Jupiters was it possible to obtain observational characteristics of their atmospheres. Many of the known hot Jupiters are eclipsing their host stars, so, from their light curve and spectral data obtained during an eclipse, it became possible to obtain information about their shape and their atmospheric composition. Thus it is possible to conclude that hot Jupiters are a common type of exoplanet, having no analogues in the solar system. Many aspects of their evolution and internal structure remain unclear. Being very close to their host stars, hot Jupiters must interact with the stellar wind and stellar magnetic field, as well as with stellar flares and coronal mass ejections, allowing researchers to gather information about them. According to UV observations, at least a fraction of hot Jupiters have extended gaseous envelopes, extending far beyond of their upper atmospheres. The envelopes are observable with current astronomical instruments, so it is possible to develop their astrophysical models. The history of hot Jupiter atmosphere studies during the past 20 years and the current status of modern theories describing the extended envelopes of hot Jupiters are excellent examples of the progress in understanding planetary atmospheres formation and evolution both in the solar system and in the extrasolar planetary systems.

Article

In addition to ground-based observations beginning in the 1970s, NASA’s Voyager 2 spacecraft flew by Triton in 1989, and NASA’s New Horizons spacecraft flew by Pluto in 2015. Prior to the flyby of New Horizons, Pluto and Triton were termed “sister worlds” due to what appeared to be a high degree of similarity in solid-body density, surface ices, diameter, and surface pressures. Despite being small, cold, icy bodies, both Pluto and Triton have been found to have atmospheres that behave as a continuous fluid up to 300 km altitude above the surface and thereby have a defined temperature, surface pressure, and global general circulation (wind). The primary constituent of these atmospheres is molecular nitrogen, with methane and carbon monoxide comprising the largest abundances of trace gases. The surface pressure as measured in the 2010s on both worlds is of the order of 10 microbars (1 Pa = 10 µbar), for these exotic atmospheres exchange mass between sublimation of surface ice and deposition of nitrogen over the course of each body’s year. Ground-based stellar occultation measurements observed a dramatic change in surface pressure, which one study found was as much as a factor of two increase between 1988 and 2003 on Pluto, presumably due to Pluto’s seasonal volatile cycle. Voyager 2 observed plumes and surface “streaks” on Triton, while New Horizons observed dunes (indicating wind speeds of 1–10 m s−1) as well as streaks, evidently indicating the presence of surface and near-surface winds. While wind velocity aloft has not been directly measured on Pluto or Triton, 3-D general circulation modeling studies of both worlds have shown zonal (east–west) wind speeds of the order of 10 m/s, meridional (north–south) wind speeds of the order of 1 m/s, and extremely weak vertical wind speeds. In 2015, New Horizons showed that Pluto and Triton were much more different than previously thought. New Horizons uncovered many spectacular views of Pluto’s atmosphere. First, while hydrocarbon haze was observed on Triton, Pluto had multiple, very distinct stratified haze layers bearing a similar appearance to the layers of an onion. Second, Pluto’s surface elevation was found to be largely inhomogeneous (in contrast to Triton) in the form of a large depression (Sputnik Planitia). Third, the characteristics of the surface markings on Pluto were found to be different than the streaks observed on Triton, which has implications for surface wind patterns. Further major discoveries made by New Horizons included evidence for many hydrocarbon species in trace concentrations, a lower than expected surface pressure, which could previously only be indirectly ascertained from ground-based observations, and a higher mixing ratio of methane at higher altitudes than at lower due to gravitational diffusive separation. Using radio occultation experiments (not conducted by Voyager 2 at Triton), New Horizons confirmed the existence of a stratosphere (temperature increasing with height) extending to 25 km altitude at both the entry and exit locations. The entry location had a shallow troposphere (temperature decreasing with height) extending to 3.5 km altitude above the surface, while the exit location did not.

Article

Climate change influences the Baltic Sea ecosystem via its effects on oceanography and biogeochemistry. Sea surface temperature has been projected to increase by 2 to 4 °C until 2100 due to global warming; the changes will be more significant in the northern areas and less so in the south. The warming up will also diminish the annual sea ice cover by 57% to 71%, and ice season will be one to three months shorter than in the early 21st century, depending on latitude. A significant decrease in sea surface salinity has been projected because of an increase in rainfall and decrease of saline inflows into the Baltic Sea. The increasing surface flow has, in turn, been projected to increase leaching of nutrients from the soil to the watershed and eventually into the Baltic Sea. Also, acidification of the seawater and sea-level rise have been predicted. Increasing seawater temperature speeds up metabolic processes and increases growth rates of many secondary producers. Species associated with sea ice, from salt brine microbes to seals, will suffer. Due to the specific salinity tolerances, species’ geographical ranges may shift by tens or hundreds of kilometres with decreasing salinity. A decrease in pH will slow down calcification of bivalve shells, and higher temperatures also alleviate establishment of non-indigenous species originating from more southern sea areas. Many uncertainties still remain in predicting the couplings between atmosphere, oceanography and ecosystem. Especially projections of many oceanographic parameters, such as wind speeds and directions, the mean salinity level, and density stratification, are still ambiguous. Also, the effects of simultaneous changes in multiple environmental factors on species with variable preferences to temperature, salinity, and nutrient conditions are difficult to project. There is, however, enough evidence to claim that due to increasing runoff of nutrients from land and warming up of water, primary production and sedimentation of organic matter will increase; this will probably enhance anoxia and release of phosphorus from sediments. Such changes may keep the Baltic Sea in an eutrophicated state for a long time, unless strong measures to decrease nutrient runoff from land are taken. Changes in the pelagic and benthic communities are anticipated. Benthic communities will change from marine to relatively more euryhaline communities and will suffer from hypoxic events. The projected temperature increase and salinity decline will contribute to maintain the pelagic ecosystem of the Central Baltic and the Gulf of Finland in a state dominated by cyanobacteria, flagellates, small-sized zooplankton and sprat, instead of diatoms, large marine copepods, herring, and cod. Effects vary from area to area, however. In particular the Bothnian Sea, where hypoxia is less common and rivers carry a lot of dissolved organic carbon, primary production will probably not increase as much as in the other basins. The coupled oceanography-biogeochemistry ecosystem models have greatly advanced our understanding of the effects of climate change on marine ecosystems. Also, studies on climate associated “regime shifts” and cascading effects from top predators to plankton have been fundamental for understanding of the response of the Baltic Sea ecosystem to anthropogenic and climatic stress. In the future, modeling efforts should be focusing on coupling of biogeochemical processes and lower trophic levels to the top predators. Also, fine resolution species distribution models should be developed and combined with 3-D modelling, to describe how the species and communities are responding to climate-induced changes in environmental variables.

Article

Classic paradigms describing meteorological phenomena and climate have changed dramatically over the last half-century. This is particularly true for the continent of Africa. Our understanding of its climate is today very different from that which prevailed as recently as the 1960s or 1970s. This article traces the development of relevant paradigms in five broad areas: climate and climate classification, tropical atmospheric circulation, tropical rain-bearing systems, climatic variability and change, and land surface processes and climate. One example is the definition of climate. Originally viewed as simple statistical averages, it is now recognized as an environmental variable with global linkages, multiple timescales of variability, and strong controls via earth surface processes. As a result of numerous field experiments, our understanding of tropical rainfall has morphed from the belief in the domination by local thunderstorms to recognition of vast systems on regional to global scales. Our understanding of the interrelationships with land surface processes has also changed markedly. The simple Charney hypothesis concerning albedo change and the related concept of desertification have given way to a broader view of land–atmosphere interaction. In summary, there has been a major evolution in the way we understand climate, climatic variability, tropical rainfall regimes and rain-bearing systems, and potential human impacts on African climate. Each of these areas has evolved in complexity and understanding, a result of an explosive growth in research and the availability of such investigative tools as satellites, computers, and numerical models.

Article

Even though many features of the vegetation and of the soil moisture distribution over Africa reflect its climatic zones, the land surface has the potential to feed back on the atmosphere and on the climate of Africa. The land surface and the atmosphere communicate via the surface energy budget. A particularly important control of the land surface, besides its control on albedo, is on the partitioning between sensible and latent heat flux. In a soil moisture-limited regime, for instance, an increase in soil moisture leads to an increase in latent heat flux at the expanse of the sensible heat flux. The result is a cooling and a moistening of the planetary boundary layer. On the one hand, this thermodynamically affects the atmosphere by altering the stability and the moisture content of the vertical column. Depending on the initial atmospheric profile, convection may be enhanced or suppressed. On the other hand, a confined perturbation of the surface state also has a dynamical imprint on the atmospheric flow by generating horizontal gradients in temperature and pressure. Such gradients spin up shallow circulations that affect the development of convection. Whereas the importance of such circulations for the triggering of convection over the Sahel region is well accepted and well understood, the effect of such circulations on precipitation amounts as well as on mature convective systems remains unclear. Likewise, the magnitude of the impact of large-scale perturbations of the land surface state on the large-scale circulation of the atmosphere, such as the West African monsoon, has long been debated. One key issue is that such interactions have been mainly investigated in general circulation models where the key involved processes have to rely on uncertain parameterizations, making a definite assessment difficult.

Article

Steven R. Cranmer

The Sun continuously expels a fraction of its own mass in the form of a steadily accelerating outflow of ionized gas called the “solar wind.” The solar wind is the extension of the Sun’s hot (million-degree Kelvin) outer atmosphere that is visible during solar eclipses as the bright and wispy corona. In 1958, Eugene Parker theorized that a hot corona could not exist for very long without beginning to accelerate some of its gas into interplanetary space. After more than half a century, Parker’s idea of a gas-pressure-driven solar wind still is largely accepted, although many questions remain unanswered. Specifically, the physical processes that heat the corona have not yet been identified conclusively, and the importance of additional wind-acceleration mechanisms continue to be investigated. Variability in the solar wind also gives rise to a number of practical “space weather” effects on human life and technology, and there is still a need for more accurate forecasting. Fortunately, recent improvements in both observations (with telescopes and via direct sampling by space probes) and theory (with the help of ever more sophisticated computers) are leading to new generations of predictive and self-consistent simulations. Attempts to model the origin of the solar wind are also leading to new insights into long-standing mysteries about turbulent flows, magnetic reconnection, and kinetic wave-particle resonances.

Article

In the years following the Second World War, the U.S. government played a prominent role in the support of basic scientific research. The National Science Foundation (NSF) was created in 1950 with the primary mission of supporting fundamental science and engineering, excluding medical sciences. Over the years, the NSF has operated from the “bottom up,” keeping close track of research around the United States and the world while maintaining constant contact with the research community to identify ever-moving horizons of inquiry. In the 1950s the field of meteorology was something of a poor cousin to the other branches of science; forecasting was considered more of trade than a discipline founded on sound theoretical foundations. Realizing the importance of the field to both the economy and national security, the NSF leadership made a concerted effort to enhance understanding of the global atmospheric circulation. The National Center for Atmospheric Research (NCAR) was established to complement ongoing research efforts in academic institutions; it has played a pivotal role in providing observational and modeling tools to the emerging cadre of researchers in the disciplines of meteorology and atmospheric sciences. As understanding of the predictability of the coupled atmosphere-ocean system grew, the field of climate science emerged as a natural outgrowth of meteorology, oceanography, and atmospheric sciences. The NSF played a leading role in the implementation of major international programs such as the International Geophysical Year (IGY), the Global Weather Experiment, the World Ocean Circulation Experiment (WOCE) and Tropical Ocean Global Atmosphere (TOGA). Through these programs, understanding of the coupled climate system comprising atmosphere, ocean, land, ice-sheet, and sea ice greatly improved. Consistent with its mission, the NSF supported projects that advanced fundamental knowledge of forcing and feedbacks in the coupled atmosphere-ocean-land system. Research projects have included theoretical, observational, and modeling studies of the following: the general circulation of the stratosphere and troposphere; the processes that govern climate; the causes of climate variability and change; methods of predicting climate variations; climate predictability; development and testing of parameterization of physical processes; numerical methods for use in large-scale climate models; the assembly and analysis of instrumental and/or modeled climate data; data assimilation studies; and the development and use of climate models to diagnose and simulate climate variability and change. Climate scientists work together on an array of topics spanning time scales from the seasonal to the centennial. The NSF also supports research on the natural evolution of the earth’s climate on geological time scales with the goal of providing a baseline for present variability and future trends. The development of paleoclimate data sets has resulted in longer term data for evaluation of model simulations, analogous to the evaluation using instrumental observations. This has enabled scientists to create transformative syntheses of paleoclimate data and modeling outcomes in order to understand the response of the longer-term and higher magnitude variability of the climate system that is observed in the geological records. The NSF will continue to address emerging issues in climate and earth-system science through balanced investments in transformative ideas, enabling infrastructure and major facilities to be developed.

Article

Biomass burning is widespread in sub-Saharan Africa, which harbors more than half of global biomass burning activity. These African open fires are mostly induced by humans for various purposes, ranging from agricultural land clearing and residue burning to deforestation. They affect a wide variety of land ecosystems, including forests, woodlands, shrublands, savannas, grasslands, and croplands. Satellite observations show that fires are distributed almost equally between the northern and southern hemispheres of sub-Saharan Africa, with a dipole-type annual distribution pattern, peaking during the dry (winter) season of either hemisphere. The widespread nature of African biomass burning and the tremendous amounts of particulate and gas-phase emissions the fires produce have been shown to affect a variety of processes that ultimately impact the earth’s atmospheric composition and chemistry, air quality, water cycle, and climate in a significant manner. However, there is still a high level of uncertainty in the quantitative characterization of biomass burning, and its emissions and impacts in Africa and globally. These uncertainties can be potentially alleviated through improvements in the spatial and temporal resolutions of satellite observations, numerical modeling and data assimilation, complemented by occasional field campaigns. In addition, there is great need for the general public, policy makers, and funding organizations within Africa to recognize the seriousness of uncontrolled biomass burning and its potential consequences, in order to bring the necessary human and financial resources to bear on essential policies and scientific research activities that can effectively address the threats posed by the combined adverse influences of the changing climate, biomass burning, and other environmental challenges in sub-Saharan Africa.

Article

N. Achilleos, L. C. Ray, and J. N. Yates

The process of magnetosphere-ionosphere coupling involves the transport of vast quantities of energy and momentum between a magnetized planet and its space environment, or magnetosphere. This transport involves extended, global sheets of electrical current, which flows along magnetic field lines. Some of the charged particles, which carry this current rain down onto the planet’s upper atmosphere and excite aurorae–beautiful displays of light close to the magnetic poles, which are an important signature of the physics of the coupling process. The Earth, Jupiter, and Saturn all have magnetospheres, but the detailed physical origin of their auroral emissions differs from planet to planet. The Earth’s aurora is principally driven by the interaction of its magnetosphere with the upstream solar wind—a flow of plasma continually emanating from the Sun. This interaction imposes a particular pattern of flow on the plasma within the magnetosphere, which in turn determines the morphology and intensity of the currents and aurorae. Jupiter, on the other hand, is a giant rapid rotator, whose main auroral oval is thought to arise from the transport of angular momentum between the upper atmosphere and the rotating, disc-like plasma in the magnetosphere. Saturn exhibits auroral behavior consistent with a solar wind–related mechanism, but there is also regular variability in Saturn’s auroral emissions, which is consistent with rotating current systems that transport energy between the magnetospheric plasma and localized vortices of flow in the upper atmosphere/ionosphere.

Article

E.R. Priest

Solar physics is one of the liveliest branches of astrophysics at the current time, with many major advances that have been stimulated by observations from a series of space satellites and ground-based telescopes as well as theoretical models and sophisticated computational experiments. Studying the Sun is of key importance in physics for two principal reasons. Firstly, the Sun has major effects on the Earth and on its climate and space weather, as well as other planets of the solar system. Secondly, it represents a Rosetta stone, where fundamental astrophysical processes can be investigated in great detail. Yet, there are still major unanswered questions in solar physics, such as how the magnetic field is generated in the interior by dynamo action, how magnetic flux emerges through the solar surface and interacts with the overlying atmosphere, how the chromosphere and corona are heated, how the solar wind is accelerated, how coronal mass ejections are initiated and how energy is released in solar flares and high-energy particles are accelerated. Huge progress has been made on each of these topics since the year 2000, but there is as yet no definitive answer to any of them. When the answers to such puzzles are found, they will have huge implications for similar processes elsewhere in the cosmos but under different parameter regimes.

Article

The planetary boundary layer of Mars is a crucial component of the Martian climate and meteorology, as well as a key driver of the surface-atmosphere exchanges on Mars. As such, it is explored by several landers and orbiters; high-resolution atmospheric modeling is used to interpret the measurements by those spacecrafts. The planetary boundary layer of Mars is particularly influenced by the strong radiative control of the Martian surface and, as a result, features a more extreme version of planetary boundary layer phenomena occurring on Earth. In daytime, the Martian planetary boundary layer is highly turbulent, mixing heat and momentum in the atmosphere up to about 10 kilometers from the surface. Daytime convective turbulence is organized as convective cells and vortices, the latter giving rise to numerous dust devils when dust is lifted and transported in the vortex. The nighttime planetary boundary layer is dominated by stable-layer turbulence, which is much less intense than in the daytime, and slope winds in regions characterized by uneven topography. Clouds and fogs are associated with the planetary boundary layer activity on Mars.

Article

Edik Dubinin, Janet G. Luhmann, and James A. Slavin

Knowledge about the solar wind interactions of Venus, Mars, and Mercury is rapidly expanding. While the Earth is also a terrestrial planet, it has been studied much more extensively and in far greater detail than its companions. As a result we direct the reader to specific references on that subject for obtaining an accurate comparative picture. Due to the strength of the Earth’s intrinsic dipole field, a relatively large volume is carved out in interplanetary space around the planet and its atmosphere. This “magnetosphere” is regarded as a shield from external effects, but in actuality much energy and momentum are channeled into it, especially at high latitudes, where the frequent interconnection between the Earth’s magnetic field and the interplanetary field allows some access by solar wind particles and electric fields to the upper atmosphere and ionosphere. Moreover, reconnection between oppositely directed magnetic fields occurs in Earth’s extended magnetotail—producing a host of other phenomena including injection of a ring current of energized internal plasma from the magnetotail into the inner magnetosphere—creating magnetic storms and enhancements in auroral activity and related ionospheric outflows. There are also permanent, though variable, trapped radiation belts that strengthen and decay with the rest of magnetospheric activity—depositing additional energy into the upper atmosphere over a wider latitude range. Virtually every aspect of the Earth’s solar wind interaction, highly tied to its strong intrinsic dipole field, has its own dedicated textbook chapters and review papers. Although Mercury, Venus, Earth, and Mars belong to the same class of rocky terrestrial planets, their interaction with solar wind is very different. Earth and Mercury have the intrinsic, mainly dipole magnetic field, which protects them from direct exposure by solar wind. In contrast, Venus and Mars have no such shield and solar wind directly impacts their atmospheres/ionospheres. In the first case, intrinsic magnetospheric cavities with a long tail are found. In the second case, magnetospheres are also formed but are generated by the electric currents induced in the conductive ionospheres. The interaction of solar wind with terrestrial planets also varies due to changes caused by different distances to the Sun and large variations in solar irradiance and solar wind parameters. Other important planetary differences like local strong crustal magnetization on Mars and almost total absence of the ionosphere on Mercury create new essential features to the interaction pattern. Solar wind might be also a feasible driver for planetary atmospheric losses of volatiles, which could historically affect the habitability of the terrestrial planets.

Article

Mario Trieloff

Although the second most abundant element in the cosmos is helium, noble gases are also called rare gases. The reason is that they are not abundant on terrestrial planets like the Earth, which is characterized by orders of magnitude depletion of—particularly light—noble gases when compared to the cosmic element abundance pattern. Indeed, geochemical depletion and enrichment processes mean that noble gases are highly versatile tracers of planetary formation and evolution. When our solar system formed—or even before—small grains and first condensates incorporated small amounts of noble gases from the surrounding gas of solar composition, resulting in depletion of light He and Ne relative to heavy Ar, Kr, and Xe, leading to the “planetary type” abundance pattern. Further noble gas depletion occurred during flash heating of mm- to cm-sized objects (chondrules and calcium, aluminum-rich inclusions), and subsequently during heating—and occasionally differentiation—on small planetesimals, which were precursors of planets. Some of these objects are present today in the asteroid belt and are the source of many meteorites. Many primitive meteorites contain very small (micron to sub-micron size) rare grains that are older than our Solar System and condensed billions of years ago in in the atmospheres of different stars, for example, Red Giant stars. These grains are characterized by nucleosynthetic anomalies, in particular the noble gases, such as so-called s-process xenon. While planetesimals acquired a depleted noble gas component strongly fractionated in favor of heavy noble gases, the Sun and also gas giants like Jupiter attracted a much larger amount of gas from the protosolar nebula by gravitational capture. This resulted in a cosmic or “solar type” abundance pattern, containing the full complement of light noble gases. In contrast, terrestrial planets accreted from planetesimals with only minor contributions from the gaseous component of the protosolar nebula, which accounts for their high degree of depletion and essentially “planetary” elemental abundance pattern. The strong depletion in noble gases facilitates their application as noble gas geo- and cosmochronometers; chronological applications are based on being able to determine noble gas isotopes formed by radioactive decay processes, for example, 40Ar by 40K decay, 129Xe by 129I decay, or fission Xe from 238U or 244Pu decay. Particularly ingrowth of radiogenic xenon is only possible due to the depletion of primordial nuclides, which allows insight into the chronology of fractionation of lithophile parent nuclides and atmophile noble gas daughters. Applied to large-scale planetary reservoirs, this helps to elucidate the timing of mantle degassing and evolution of planetary atmospheres. Applied to individual rocks and minerals, it allows radioisotope chronology using short-lived (e.g., 129I–129Xe) or long-lived (e.g., 40K–40Ar) systems. The dominance of 40Ar in the terrestrial atmosphere allowed von Weizsäcker to conclude that most of the terrestrial atmosphere originated by degassing of the solid Earth, which is an ongoing process today at mid-ocean ridges, as indicated by outgassing of primordial helium from newly forming ocean crust. Mantle degassing was much more massive in the past, with most of the terrestrial atmosphere probably formed during the first few 100 million years of Earth’s history, in response to major evolutionary processes of accretion, terrestrial core formation, and the terminal accretion stage of a giant impact that formed our Moon. During accretion, solar noble gases were added to the mantle, presumably by solar wind irradiation of the small planetesimals and dust accreting to form the Earth. While the Moon-forming impact likely dissipated a major fraction of the primordial atmosphere, today’s atmosphere originated by addition of a late veneer of asteroidal and possibly cometary material combined with a decreasing rate of mantle degassing over time. As other atmophile elements behave similarly to noble gases, they also trace the origin of major volatiles on Earth, for example, water, nitrogen, and carbon.

Article

Valery I. Shematovich and Dmitry V. Bisikalo

The uppermost layers of a planetary atmosphere, where the density of neutral particles is vanishingly low, are commonly called exosphere or planetary corona. Since the atmosphere is not completely bound to the planet by the planetary gravitational field, light atoms, such as hydrogen and helium, with sufficiently large thermal velocities can escape from the upper atmosphere into interplanetary space. This process is commonly called Jeans escape and depends on the temperature of the ambient atmospheric gas at an altitude where the atmospheric gas is virtually collisionless. The heavier carbon, nitrogen, and oxygen atoms can populate the coronas and escape from the atmospheres of terrestrial planets only through nonthermal processes such as photo- and electron-impact energizing, charge exchange, atmospheric sputtering, and ion pickup. The observations reveal that the planetary coronae contain both a fraction of thermal neutral particles with a mean kinetic energy corresponding to the exospheric temperature and a fraction of hot neutral particles with mean kinetic energy much higher than that expected for the exospheric temperature. These suprathermal (hot) atoms and molecules are the direct manifestation of the nonthermal processes taking place in the atmospheres. These hot particles populate the hot coronas, take a major part in the atmospheric escape, produce nonthermal emissions, and react with the ambient atmospheric gas, triggering the hot atom chemistry.

Article

Mikhail Zolotov

Chemical and phase compositions of the surface of Venus could reflect a history of gas–rock and fluid–rock interactions, recent and past climate changes, and a loss of water from the Earth’s sister planet. The concept of chemical weathering on Venus through gas–solid type reactions was established in the early 1960s after the discovery of the hot and dense CO2-rich atmosphere of the planet, inferred from Earth-based and Mariner 2 radio emission data. Initial models suggested carbonation, hydration, and oxidation of exposed igneous rocks and a control (buffering) of atmospheric gases by solid–gas type chemical equilibria in the near-surface rocks. Carbonates, phyllosilicates and Fe oxides were considered likely secondary minerals. From the late 1970s onward, measurements of trace gases in the sub-cloud atmosphere by the Pioneer Venus and Venera entry probes and by Earth-based infrared spectroscopy challenged the likelihood of hydration and carbonation. The atmospheric H2O gas content appeared to be low enough to allow the stable existence of H2O-bearing and a majority of OH-bearing minerals. The concentration of SO2 gas was too high to allow the stability of Ca-rich carbonates and silicates with respect to sulfatization to CaSO4. In the 1980s, the detection of an elevated bulk S content at the Venera and Vega landing sites suggested ongoing consumption of atmospheric SO2 to surface sulfates. The supposed composition of the near-surface atmosphere implied oxidation of ferrous minerals to Fe oxides, magnetite and hematite, consistent with the infrared reflectance of surface materials. The likelihood of sulfatization and oxidation has been illustrated in modeling experiments in simulated Venus’ conditions. The morphology of Venus’ surface suggests contact of atmospheric gases with hot surface materials of mainly basaltic composition during the several hundreds of millions years since a global volcanic/tectonic resurfacing. Some exposed materials could have reacted at higher and lower temperatures in a presence of diverse gases at different altitudinal, volcanic, impact, and atmospheric settings. On highly deformed tessera terrains, more ancient rocks of unknown composition may reflect interactions with putative water-rich atmospheres and even aqueous solutions. Geological formations rich in salt, carbonate, Fe oxide, or silica will indicate past aqueous processes. The apparent diversity of affected solids, surface temperatures, pressures, and gas/fluid compositions throughout Venus’ history implies multiple signs of chemical alterations that remain to be investigated. The current understanding of chemical weathering is limited by the uncertain composition of the deep atmosphere, by the lack of direct data on the phase and chemical composition of surface materials, and by the uncertain data on thermodynamics of minerals and their solid solutions. In preparation for further atmospheric entry probe and lander missions, rock alteration could be investigated through chemical kinetic experiments and calculations of solid-gas/fluid equilibria to constrain past and present processes.

Article

The atmosphere of Venus is quite different from that of Earth: it is much hotter and denser. The temperature and pressure at the surface are 740 K and 92 atmospheres respectively. Its atmosphere is primarily composed of carbon dioxide (96.5%) and nitrogen (3.5%), the rest being trace gases such as carbon monoxide (CO), water vapor (H2O), halides (HF, HCl), sulfur-bearing species (SO2, SO, OCS, H2S), and noble gases. Sulfur compounds are extremely important in understanding the formation of the Venusian clouds which are believed to be composed of sulfuric acid (H2SO4) droplets. These clouds completely enshroud the planet in a series of layers, extending from 50 to 70 km altitude, and are composed of particles of different sizes and different H2SO4/H2O compositions. These act as a very effective separator between the atmospheres below and above the clouds, which show very distinctive characteristics.